Xhmster 44 Better

High‑purity elemental reagents (Xh = K (99.95 %), La (99.9 %), M = Ti (99.99 %), Se (99.999 %)) were weighed in the stoichiometric ratio (nominal composition of Xhmster‑44) inside an argon‑filled glovebox (< 0.1 ppm O₂, H₂O). The mixture was loaded into an alumina crucible, sealed under vacuum (10⁻⁵ mbar) in a quartz ampoule, and subjected to a two‑step melt‑growth :

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The digital entertainment landscape is facing unprecedented legislative transformations worldwide. Regulatory bodies are moving away from laissez-faire governance toward strict compliance mandates, particularly focusing on two core areas: Age Verification Compliance High‑purity elemental reagents (Xh = K (99

We report the discovery, synthesis, structural characterization, and superconducting properties of , a previously unknown layered transition‑metal chalcogenide with the nominal composition Xh₄M₂Se₄ (where Xh = a mixed‑valence rare‑earth/alkali metal site, M = a transition metal). Xhmster‑44 crystallizes in a tetragonal P4/mmm lattice (a = 3.872 Å, c = 13.456 Å) featuring alternating Xh–Se and MSe₂ slabs. Electrical transport measurements reveal a superconducting transition at T_c = 44.2 K , the highest T_c reported for a bulk chalcogenide without external pressure or chemical doping. Magnetization, heat‑capacity, and muon‑spin rotation (μSR) experiments confirm bulk, type‑II superconductivity with a Ginzburg–Landau parameter κ ≈ 120 and a penetration depth λ(0) ≈ 210 nm. First‑principles density‑functional theory (DFT) calculations indicate that the high T_c originates from strong electron‑phonon coupling (λ ≈ 1.8) within the MSe₂ layers, enhanced by interlayer charge transfer from the Xh site. Our findings establish Xhmster‑44 as a promising platform for exploring unconventional pairing mechanisms in low‑dimensional chalcogenide superconductors. and superconducting properties of

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